We present high-resolution (R similar to 1500-2000) spectra of the 4.27 mum
asymmetric stretching feature of solid CO2 in eight lines of sight observe
d with the Short Wavelength Spectrometer of the Infrared Space Observatory.
Two of the sources are field stars located behind the Taurus molecular clo
ud; the others are young stellar objects (YSOs) of predominantly low-to-int
ermediate mass. We find a significant source-to-source variation in the sol
id CO2/H2O abundance ratio in our sample: two lines of sight, Elias 18 and
RAFGL 989, have CO2 abundances of similar to 34%-37%, considerably higher t
han in other lines of sight studied to date. In agreement with a previous s
tudy of Elias 16, we confirm a substantial (similar to 20%) abundance of so
lid CO2 relative to H2O in the quiescent intracloud medium. We compare the
CO2 profiles with laboratory spectra of interstellar ice analogs from the L
eiden Observatory Laboratory database. Results show that the 4.27 um profil
es toward field stars and embedded low-mass objects are remarkably similar
to each other and seem to originate mostly in cold H2O-rich ice. In two hig
her mass YSOs (RAFGL 989 and S255 IRS1), the profiles are clearly different
, and at least the latter source shows signs of thermal processing.