I discuss the role played by the spin-network basis and recoupling the
ory (in its graphical tangle-theoretic formulation) and their use in p
erforming explicit calculations in loop quantum gravity. In particular
, I show that recoupling theory allows the derivation of explicit expr
essions for the eigenvalues of the quantum volume operator. An importa
nt side result of these computations is the determination of a scalar
product with respect to which area and volume operators are symmetric,
and the spin network states orthonormal.