Two-dimensional growth of GaN thin films on an atomically flat C-face 6H-Si
C(000 (1) over bar) surface prepared by ultra, high vacuum Si-etching is ob
served when using an AIN buffer layer in N plasma-assisted molecular beam e
pitaxy. Scanning tunneling microscopy and reflection high energy electron d
iffraction observations reveal a series of Ga-stabilized reconstructions wh
ich are consistent with those reported for an N-polar GaN(000 (1) over bar)
film. The result, including the effect observed previously for GaN thin fi
lm on Si-terminated 6H-SiC(0001), agrees with the polarity assignment of he
teroepitaxial wurtzite GaN films on polar 6H-SiC substrates, i.e., GaN film
grown on SiC(000 (1) over bar) is < 000<(1)over bar> > oriented (N-face) w
hile that on SiC(0001) is < 0001 > oriented (Ga-face).