Citation
Df. Taber et Pv. Joshi, Free radical generation by reduction of ketone tosylhydrazones, CR AC S IIC, 4(7), 2001, pp. 557-560
Citations number
15
Categorie Soggetti
Chemistry
Journal title
COMPTES RENDUS DE L ACADEMIE DES SCIENCES SERIE II FASCICULE C-CHIMIE
ISSN journal
13871609
→ ACNP
Volume
4
Issue
7
Year of publication
2001
Pages
557 - 560
Database
ISI
SICI code
1387-1609(200107)4:7<557:FRGBRO>2.0.ZU;2-L
Abstract
Alkyl radicals are conveniently generated from ketones by reduction of the
derived tosylhydrazones. The alkyl radicals undergo efficient intramolecula
r cyclization to give the thermodynamically less stable cis-1,2-dialkylcycl
opentane derivatives. (C) 2001 Academie des sciences / Editions scientifiqu
es et medicates Elsevier SAS.