Determination of the rate constant of hydrogen transfer by di-n-butyl-4,7,10-trioxaundecylstannane to primary alkyl radicals

Authors
Ferkous, F Degueil-Castaing, M Deleuze, H Maillard, B
Citation
F. Ferkous et al., Determination of the rate constant of hydrogen transfer by di-n-butyl-4,7,10-trioxaundecylstannane to primary alkyl radicals, CR AC S IIC, 4(7), 2001, pp. 561-565
Citations number
28
Categorie Soggetti
Chemistry
Journal title
COMPTES RENDUS DE L ACADEMIE DES SCIENCES SERIE II FASCICULE C-CHIMIE
ISSN journal
13871609 → ACNP
Volume
4
Issue
7
Year of publication
2001
Pages
561 - 565
Database
ISI
SICI code
1387-1609(200107)4:7<561:DOTRCO>2.0.ZU;2-Q
Abstract
The rate constant of hydrogen transfer by dibutyl 4,7,10-trioxaundecylstann ane to primary alkyl radicals was determined at different temperatures by t he study of the free radical reduction of 6-bromo-1-hexene by this stannane . This work shows that this compound is an excellent substitute to tri-n-bu tyltinhydride. (C) 2001 Academie des sciences / Editions scientifiques et m edicales Elsevier SAS.