REACTION OF RING AND SIDE-CHAIN SUBSTITUTED 3-PHOSPHONOMETHYLCYCLOHEXENONES WITH AZIDOSILANE REAGENTS

Authors
MPHAHLELE MJ
Citation
Mj. Mphahlele, REACTION OF RING AND SIDE-CHAIN SUBSTITUTED 3-PHOSPHONOMETHYLCYCLOHEXENONES WITH AZIDOSILANE REAGENTS, Phosphorus, sulfur and silicon and the related elements, 118, 1996, pp. 145-154
Citations number
9
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Phosphorus, sulfur and silicon and the related elements → ACNP
ISSN journal
10426507
Volume
118
Year of publication
1996
Pages
145 - 154
Database
ISI
SICI code
1042-6507(1996)118:<145:RORASS>2.0.ZU;2-#
Abstract
Ring and side chain substituted 3-phosphonomethylcyclohexenones react with triazidochlorosilane (TACS) in acetonitrile or azidotrimethylsila ne (TMS-N-3)/iodine/pyridine mixture in dichloromethane to afford ring expanded tetrazolo and gamma-iodo-delta-ketoalk-2-enylphosphonate sys tems, respectively.