NEW STRATEGY FOR THE SYNTHESIS OF THIOLS

Citation
Ra. Bekker et Vy. Popkova, NEW STRATEGY FOR THE SYNTHESIS OF THIOLS, Phosphorus, sulfur and silicon and the related elements, 119, 1996, pp. 161-168
Citations number
19
Categorie Soggetti
Chemistry Inorganic & Nuclear
ISSN journal
10426507
Volume
119
Year of publication
1996
Pages
161 - 168
Database
ISI
SICI code
1042-6507(1996)119:<161:NSFTSO>2.0.ZU;2-R
Abstract
A new, general, one-step method for the synthesis of fluorine-containi ng thiols is reported. It consists of the reduction of the correspondi ng sulfenyl chlorides by an excess of hydrogen sulfide in an autoclave at room temperature. The method is notable for the simplicity of exec ution, the easiness of isolation of the final products in individual s tate, the absence of by-products, and the high yields.