HIGH-RESOLUTION SOLID-STATE F-19 AND N-15 MAS NMR-SPECTRA OF FLUOROAROMATICS AND AROMATIC NITROGEN-HETEROCYCLES PHYSISORBED ON SILICA AND ALUMINA

Citation
G. Vonfircks et al., HIGH-RESOLUTION SOLID-STATE F-19 AND N-15 MAS NMR-SPECTRA OF FLUOROAROMATICS AND AROMATIC NITROGEN-HETEROCYCLES PHYSISORBED ON SILICA AND ALUMINA, Journal of organic chemistry, 62(15), 1997, pp. 5074-5079
Citations number
50
Categorie Soggetti
Chemistry Inorganic & Nuclear
ISSN journal
00223263
Volume
62
Issue
15
Year of publication
1997
Pages
5074 - 5079
Database
ISI
SICI code
0022-3263(1997)62:15<5074:HSFANM>2.0.ZU;2-O
Abstract
High-resolution F-19 and N-15 solid State MAS NMR spectra have been ob tained for fluoro-substituted aromatics and for aromatic nitrogen hete rocycles, respectively, adsorbed on silica and alumina, where line nar rowing is due to the high mobility of these systems on the surface of the porous materials. F-19,F-19 COSY, F-19,C-13 HETCOR, and F-19 --> C -13 INEPT experiments were successfully performed, and N-15 NMR was me asured in natural abundance.