It is shown how the performances of SAW gas sensors can be optimized based
on pure acoustic peculiarities of SAW propagation in anisotropic single cry
stals. For a given gas and sensitive membrane, the calibration curve (depen
dence of the response R versus gas concentration n), the sensitivity S (slo
pe of the calibration curve: S = dR/dn), the detection limit n(thr) (cut-of
f of the curve at the threshold R-thr), and the resolution Deltan of the se
nsor (recognition of two close concentrations) can be controlled by a prope
r choice of the substrate material and its crystallographic orientation (cu
t and direction of the SAW propagation). An experimental test of this prope
rty is performed on SAW devices implemented on different substrate material
s and crystallographic orientations, both uncoated or coated, with a sorben
t membrane of polycrystalline Pd or Pd:Ni film, upon exposure to humid air
as a test analyte.