Ki. Momot et Cs. Johnson, Nuclear magnetic resonance radiation damping in inhomogeneous radio frequency fields: The toroid cavity detector, J CHEM PHYS, 115(9), 2001, pp. 3992-4002
A theory is presented for radiation damping (RD) in the toroid cavity nucle
ar magnetic resonance detector, a cylindrically symmetric inhomogeneous-rf
field detector in which the magnitude of B-1 is inversely proportional to t
he distance from the cylindrical symmetry axis. The equations of motion of
the magnetization components are obtained and discussed. Numerical simulati
ons of conventional- and composite-pulse experiments are presented, along w
ith a discussion of the effects of RD on the evolution of magnetization. Pr
eliminary simulations of RD in the presence of inhomogeneous line broadenin
g are also presented. The signature effect of radiation damping in the TCD
is the winding or unwinding of magnetization gratings that has recently bee
n observed by other researchers. The observed magnitude of the effect is li
nked to the effective filling factor, which currently appears to be limited
by the stray inductance of the detection circuit. The results are of inter
est in connection with recent findings regarding the interaction of RD with
the dipolar demagnetizing field. (C) 2001 American Institute of Physics.