Nuclear magnetic resonance radiation damping in inhomogeneous radio frequency fields: The toroid cavity detector

Citation
Ki. Momot et Cs. Johnson, Nuclear magnetic resonance radiation damping in inhomogeneous radio frequency fields: The toroid cavity detector, J CHEM PHYS, 115(9), 2001, pp. 3992-4002
Citations number
26
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
JOURNAL OF CHEMICAL PHYSICS
ISSN journal
00219606 → ACNP
Volume
115
Issue
9
Year of publication
2001
Pages
3992 - 4002
Database
ISI
SICI code
0021-9606(20010901)115:9<3992:NMRRDI>2.0.ZU;2-W
Abstract
A theory is presented for radiation damping (RD) in the toroid cavity nucle ar magnetic resonance detector, a cylindrically symmetric inhomogeneous-rf field detector in which the magnitude of B-1 is inversely proportional to t he distance from the cylindrical symmetry axis. The equations of motion of the magnetization components are obtained and discussed. Numerical simulati ons of conventional- and composite-pulse experiments are presented, along w ith a discussion of the effects of RD on the evolution of magnetization. Pr eliminary simulations of RD in the presence of inhomogeneous line broadenin g are also presented. The signature effect of radiation damping in the TCD is the winding or unwinding of magnetization gratings that has recently bee n observed by other researchers. The observed magnitude of the effect is li nked to the effective filling factor, which currently appears to be limited by the stray inductance of the detection circuit. The results are of inter est in connection with recent findings regarding the interaction of RD with the dipolar demagnetizing field. (C) 2001 American Institute of Physics.