ENANTIOSELECTIVE HYDROFORMYLATION OF VINYL-AROMATICS USING A RHODIUM COMPLEX WITH THE YL-1,7,7-TRIMETHYLBICYCLO[2.2.1]HEPT-2-YL)PYRIDINE

Authors
CHELUCCI G MARCHETTI M SECHI B
Citation
G. Chelucci et al., ENANTIOSELECTIVE HYDROFORMYLATION OF VINYL-AROMATICS USING A RHODIUM COMPLEX WITH THE YL-1,7,7-TRIMETHYLBICYCLO[2.2.1]HEPT-2-YL)PYRIDINE, Journal of molecular catalysis. A, Chemical, 122(2-3), 1997, pp. 111-114
Citations number
19
Categorie Soggetti
Chemistry Physical
Journal title
Journal of molecular catalysis. A, Chemical → ACNP
ISSN journal
13811169
Volume
122
Issue
2-3
Year of publication
1997
Pages
111 - 114
Database
ISI
SICI code
1381-1169(1997)122:2-3<111:EHOVUA>2.0.ZU;2-S
Abstract
The rhodium complex of a pyridylphosphinite derived from (+)-camphor w as prepared and assessed in the hydroformylation reaction of some viny l-aromatic substrates. The complex exhibit good catalytic activity. Th e prevalent formation of the branched aldehyde was obtained with all e xamined substrates. The enantioselectivities were low to moderate (up to 45%).