A. Bianconi et al., A superconductor made by a metal heterostructure at the atomic limit tunedat the 'shape resonance': MgB2, J PHYS-COND, 13(33), 2001, pp. 7383-7390
We have studied the variation of superconducting critical temperature T-c a
s a function of charge density and lattice parameters in Mg1-xAlxB2 superco
nducting samples. The AB(2) heterostucture of metallic boron layers (interc
alated by A = magnesium, aluminum layers, playing the role of spacers) is m
ade by direct chemical reaction. The spacing between boron layers and their
charge density are controlled by chemical substitution of Mg by Al atoms.
We show that high T-c superconductivity is realized by tuning the chemical
potential at a `shape resonance' according with the patent for `high-temper
ature superconductors made by metal heterostructures at the atomic limit'.
The energy width of the superconducting shape resonance is found to be abou
t 400 meV.