Electrochemical preparation of cadmium selenide nanoparticles by the use of molecular templates

We report the electrochemical preparation of cadmium selenide nanoparticles at gold electrodes modified with molecular templates. The molecular templa tes were obtained by properly arranging thiolated beta -cyclodextrin self-a ssembled monolayers (SAMs) on gold electrodes. Selenium was first deposited on a SAM-modified gold electrode at an appropriate potential, followed by reduction to HSe- in a solution containing Cd2+, leading to the deposition of CdSe. The Cd codeposited at the time of CdSe deposition was removed by a nodic dissolution at a potential where it was oxidized. Scanning electron m icroscopic pictures showed that Se-0 and cadmium selenide particles of smal ler than 60 and 150 Mm diam, respectively, were deposited on the SAM-modifi ed gold electrodes. Selenium particles of as small as 1-2 nm diam and simil ar to0.2 nm height were observed by in situ electrochemical scanning tunnel ing microscopy experiments during the early stages of electrochemical depos ition. (C) 2001 The Electrochemical Society.