Pulsed-laser polymerization in compartmentalized liquids, 2 - Miniemulsions

Authors
Jung, M van Hamersveld, EMS Julien, T van Herk, AA
Citation
M. Jung et al., Pulsed-laser polymerization in compartmentalized liquids, 2 - Miniemulsions, MACRO RAPID, 22(12), 2001, pp. 978-982
Citations number
18
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
MACROMOLECULAR RAPID COMMUNICATIONS
ISSN journal
10221336 → ACNP
Volume
22
Issue
12
Year of publication
2001
Pages
978 - 982
Database
ISI
SICI code
1022-1336(20010830)22:12<978:PPICL2>2.0.ZU;2-Q
Abstract
Communication: The propagation rate coefficient (k(p)) of methyl methacryla te has been measured in miniemulsions. The molecular weight distributions s how many higher order peaks which seems to be specific for pulsed initiatio n polymerization in compartmentalized liquids. The k(p) values are ver simi lar to bulk values although a frequency dependence is observed. This freque ncy dependence, which was overlooked in earlier research, is also present i n pulsed laser experiments in bulk.