M. Sferrazza et al., Evidence of highly localized failure within core-shell toughening particles from in-situ small-angle scattering, MACROMOLEC, 34(19), 2001, pp. 6708-6718
In-situ tensile deformation of toughened PMMA was investigated using small-
angle X-ray scattering (SAXS). The toughening particles had a three-layer s
tructure consisting of a PMMA core, a rubber shell, and a thin PMMA outer l
ayer. Uniaxial tensile stress was applied at a constant strain rate of 5 mm
/min at room temperature. Under these conditions the dominant deformation m
echanism was found to depend on the concentration of toughening particles.
When the particle concentration was low, the SAXS patterns showed that high
ly localized failure occurred inside the particles as the yield point of th
e tensile curve was reached. The failure began at the poles of the particle
s, at or immediately adjacent to the core/shell interface, and during yield
it grew around this interface. At high particle concentration the particle
s stretched without failing. No evidence for crazing was seen in any of the
scattering patterns. The major deformation mechanisms occurred inside the
toughening particles rather than in the PMMA matrix.