An unusual Bamford-Stevens reaction of 17-toluenesulfonylhydrazono-3 beta-acetoxy-14 alpha-hydroxyandrost-5-ene

Authors
Khripach, VA Zhabinskii, VN Kotyatkina, AI Fando, GP Lyakhov, AS Govorova, AA van der Louw, J Groen, MB de Groot, A
Citation
Va. Khripach et al., An unusual Bamford-Stevens reaction of 17-toluenesulfonylhydrazono-3 beta-acetoxy-14 alpha-hydroxyandrost-5-ene, MENDELEEV C, (4), 2001, pp. 144-145
Citations number
10
Categorie Soggetti
Chemistry
Journal title
MENDELEEV COMMUNICATIONS
ISSN journal
09599436 → ACNP
Issue
4
Year of publication
2001
Pages
144 - 145
Database
ISI
SICI code
0959-9436(200107/08):4<144:AUBRO1>2.0.ZU;2-B
Abstract
The Bamford-Stevens reaction of 17-toluenesulfonylhydrazono-3 beta -acetoxy -14 alpha -hydroxyandrost-5-ene was found to proceed with migration of the 18-methyl group and formation of a 13,14-epoxide.