Kinetic and stereospecific manifestations of a set of active centres in butadiene polymerization under the action of a catalytic system based on NdCl3 center dot 3TBP

Authors
Monakov, YB Sabirov, ZM Duvakina, NV Urazbaev, VN Ponomareva, OA
Citation
Yb. Monakov et al., Kinetic and stereospecific manifestations of a set of active centres in butadiene polymerization under the action of a catalytic system based on NdCl3 center dot 3TBP, MENDELEEV C, (4), 2001, pp. 157-159
Citations number
8
Categorie Soggetti
Chemistry
Journal title
MENDELEEV COMMUNICATIONS
ISSN journal
09599436 → ACNP
Issue
4
Year of publication
2001
Pages
157 - 159
Database
ISI
SICI code
0959-9436(200107/08):4<157:KASMOA>2.0.ZU;2-Q
Abstract
The unusual dependence of butadiene conversion and polymer microstructure o n the ratio Mg/Nd or Al/Nd during the polymerization of butadiene under the action of NdCl3. 3TBP-AlBu3i-MgBu(i-C8H17) can be explained by the formati on of a set of active centres in the catalytic system.