(Bi,Pb)(2.2)Sr2Ca2.2-xPrxCu3Oy silver sheathed tapes with Pr-doping amount
of x = 0.0, 0.001 and 0.002 have been prepared by powder-in-tube method. X-
ray diffraction analyses manifest that the tapes with x = 0.001 and 0.002 (
doped) have less Pb-rich phase than the tape with x = 0.0 (un-doped). Trans
mission electron microscopy images show that the Pb-rich phase particles of
similar to 40 nm are embedded in un-doped (Bi,Pb)-2223 grain matrix, while
defects induced by Pr-doping with the size smaller than that of the Pb-ric
h phase particles exist in the doped samples. As compared with the un-doped
tape, the magnetic field dependence of critical current densities of the d
oped tapes are noticeably improved at 77 K, and their irreversibility lines
are also shifted to higher temperatures and magnetic fields and activation
energies of flux motion increased drastically. The enhanced flux pinning s
eems to mainly originate from the fine normal-like defects induced by the p
artial Pr-substitution for Ca. (C) 2001 Elsevier Science B.V. All rights re
served.