The magnetic hysteresis loops were studied on Pr6O11 added top-seeded melt
grown YBa2Cu3Oy (Y123) superconductors. By tailoring the flux pinning sites
by praseodymium oxide additions, for the first time, a pronounced intermed
iate peak was observed in the magnetisation loops on melt textured Y123 mat
erial. The position of the intermediate peak was observed to shift towards
lower fields with decreasing temperature in contrast to the fish-tail peak
where the field at which the peak appears increases with decreasing tempera
ture. The origin of the intermediate peak is assigned as due to the matchin
g effect from Pr-substituted regions in the Y123 matrix. The nature and con
ditions, which favoured the appearance of the intermediate peak and the rea
sons for the shift in its position with temperature, are discussed. A schem
atic model, based on the temperature dependent pinning centres, is proposed
to explain the peak position with temperature. (C) 2001 Elsevier Science B
.V. All rights reserved.