The electronic properties of zinc-blende AlxGa1-xAsySb1-y quaternary alloys
lattice-matched to InAs have been investigated by using a pseudopotential
method under the virtual crystal approximation, which takes into account th
e effects of compositional variations in the calculations. The resulting ba
nd structures at various Al concentrations x show quite nonlinear variation
s for the main band gap energies and have been used to calculate the effect
ive masses of the electron and heavy hole. A direct to indirect band gap cr
ossover is found to occur at x = 0.28. We electron densities derived from p
seudopotential calculations are also reported.