The optical afterglow of a gamma ray burst, GRB 010222, which was discovere
d by the BeppoSAX Team as the brightest one ever detected, was observed by
Suprime-Cam of the Subaru Telescope at Mauna Kea. The obtained R-band magni
tude was 18.59 +/- 0.04 at February 22.51 UT, 18.99 +/- 0.04 at February 22
.65 UT, and 21.76 +/- 0.03 at February 25.64 UT. The light curve made from
all data reported so far shows the decay of the brightness with a broken po
wer law, of which the indices are -0.92 +/- 0.01 before and -1.27 +/- 0.01
after the break. The break point of the light curve is 0.73 +/- 0.02 d afte
r the burst, which is the earliest example ever observed. A brief summary o
f our follow-up observations, together with the importance of the optical f
ollow-up capable by the Subaru telescope. is described in this letter.