Kinetic and spectroscopic study of C2H5C(O)O-2 radicals using laser flash photolysis and UV absorption spectrometry

Citation
A. Bencsura et al., Kinetic and spectroscopic study of C2H5C(O)O-2 radicals using laser flash photolysis and UV absorption spectrometry, REACT KIN C, 73(2), 2001, pp. 291-296
Citations number
14
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
REACTION KINETICS AND CATALYSIS LETTERS
ISSN journal
01331736 → ACNP
Volume
73
Issue
2
Year of publication
2001
Pages
291 - 296
Database
ISI
SICI code
0133-1736(2001)73:2<291:KASSOC>2.0.ZU;2-1
Abstract
Rate constant for the self-combination reaction of the propionylperoxy radi cal was measured at room temperature using laser photolysis - transient abs orption technique. The observed rate coefficient is (1.44 +/- 0.14)x10(-11) cm(3) molecule(-1) s(-1) at 298 K.