Nature of hydrogenation catalysts on the basis of palladium bis-acetylacetonate and triephenylphosphine

Authors
Schmidt, FK Belykh, LB Goremyka, TV Belonogova, LN Umanets, VA
Citation
Fk. Schmidt et al., Nature of hydrogenation catalysts on the basis of palladium bis-acetylacetonate and triephenylphosphine, REACT KIN C, 73(2), 2001, pp. 391-398
Citations number
10
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
REACTION KINETICS AND CATALYSIS LETTERS
ISSN journal
01331736 → ACNP
Volume
73
Issue
2
Year of publication
2001
Pages
391 - 398
Database
ISI
SICI code
0133-1736(2001)73:2<391:NOHCOT>2.0.ZU;2-0
Abstract
The formation mechanism of microheterogeneous hydrogenation catalysts based on phosphinepalladium (II) complexes has been considered. According to ele mental analysis, X-ray diffraction, electron microscopy, NMR, and IR spectr oscopy, the catalyst is a nanoscale palladium organophosphorus matrix and ( or) palladium phosphide with immobilized palladium clusters.