Spectroscopic ellipsometry has been the technique of choice to characterize
thin films and multilayers in semiconductor manufacturing. Extending this
technology into the vacuum ultraviolet range, down to 140nm, however, for e
merging 157nm optical lithography applications, requires an environment tha
t avoids the absorbing effects of oxygen and water vapor below the 190nm wa
velength; these must be reduced to the parts/million range. In addition, th
e optical setup for VUV spectroscopic ellipsometry must put the monochromat
or in the ellipsometer's polarizer arem to avoid photobleaching, and the el
lipsometer must work in a rotating analyzer configuration to minimize paras
itic polarizations.