Solution- and solid-phase approaches in asymmetric phase-transfer catalysis by cinchona alkaloid derivatives

Authors
Thierry, B Perrard, T Audouard, C Plaquevent, JC Cahard, D
Citation
B. Thierry et al., Solution- and solid-phase approaches in asymmetric phase-transfer catalysis by cinchona alkaloid derivatives, SYNTHESIS-S, (11), 2001, pp. 1742-1746
Citations number
40
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
SYNTHESIS-STUTTGART
ISSN journal
00397881 → ACNP
Issue
11
Year of publication
2001
Pages
1742 - 1746
Database
ISI
SICI code
0039-7881(200108):11<1742:SASAIA>2.0.ZU;2-H
Abstract
The catalytic asymmetric alkylation under phase-transfer conditions of vari ous substrates (enones, alpha -fluoro ketones, glycine-imines) promoted by chiral quaternary ammonium salts derived from cinchona alkaloids is describ ed. A solvent-free phase-transfer catalysis is presented as well as a new t ype of polymer-supported phase-transfer catalyst derived from cinchona alka loids.