Direct conversion of silyl ethers or tetrahydropyranyl ethers into the corresponding diphenylmethyl ethers

Citation
T. Suzuki et al., Direct conversion of silyl ethers or tetrahydropyranyl ethers into the corresponding diphenylmethyl ethers, SYN COMMUN, 31(18), 2001, pp. 2761-2766
Citations number
14
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
SYNTHETIC COMMUNICATIONS
ISSN journal
00397911 → ACNP
Volume
31
Issue
18
Year of publication
2001
Pages
2761 - 2766
Database
ISI
SICI code
0039-7911(2001)31:18<2761:DCOSEO>2.0.ZU;2-H
Abstract
Direct conversion of alcohol silyl ethers into the corresponding diphenylme thyl (DPM) ethers can be easily performed by the reaction with diphenylmeth yl formate in the presence of a catalytic amount of trimethylsilyl trifluor omethanesulfonate. By the additional use of triethylsilane, tetrahydropyran yl ethers can be also converted into the corresponding DPM ethers.