3-Aryl-6,7-diliydro-s-triazolo[3,4-b][1,3]thiazines and 3-aryl-5,6-dihydro-
thiazolo[2,3-c]-s-triazoles were synthesized by nucleophilic substitution o
f 3-aryl-5-mercapto-1,2,4-triazoles with 1,3-dibromopropane and 1,2-dichlor
oethane. And the bis-Mannich reaction of 3-aryl-5-mercapto-1,2,4-triazoles
with formaldehyde has been studied.