A new iron indium germanate has been prepared as polycrystalline powder mat
erial which crystallizes in the monoclinic system (S.G. C2/m. No. 12). The
structure was characterized by X-ray powder diffraction and Rietveld refine
ment of the resulting diffraction pattern. The cell parameters are a = 6.51
24(4) Angstrom, b = 8.5914(5) Angstrom, c = 4.8936(3) Angstrom, beta = 102.
683(2)degrees, V = 267.12(3) Angstrom (3) and Z = 2. The structure contains
R+3 cations (R=Fe. In) almost equally distributed in distorted RO6 octahed
ral sites. These octahedra are joined by edge sharing forming a hexagonal a
rrangement on the ab planes. The RO6 octahedra layers are held together by
sheets of isolated Ge2O7 diorthogroups constituted by a double tetrahedra s
haring a common vertex. This compound has the thortveitite structure and ke
eps a strong relationship with the FeYGe2O7 germanate. which presents two R
+3 sites with six-coordinated (R = Fe) and seven-coordinated (R=Y) oxygens,
corresponding to the different symmetry given by the monoclinic space grou
p P2(1)/m (No. 11).