Defects in SiO2/Si specimens were probed by using a monoenergetic posi
tron beam. Doppler broadening profiles of the annihilation radiation w
ere measured as a function of incident positron energy for SiO2(100 nm
)/Si specimens fabricated by wet, dry and ultradry oxidation. The diff
usion of positrons in the Si substrate was found to be enhanced by an
electric field caused by positive charges near the SiO2/Si interface.
The Doppler broadening profile corresponding to the annihilation of po
sitrons in the Si substrate with the SiO2 film grown by wet oxidation
was found to be broader than those in the specimens fabricated by dry
or ultradry oxidation. This was attributed to the fact that the concen
tration of oxygen clusters in the Si substrate for the specimen fabric
ated by wet oxidation was higher than those for the specimens fabricat
ed by dry or ultradry oxidation.