Objective. By examining the developments and diverse applications of e
mission spectral analysis, it can be shown that scientific knowledge a
nd the state of analytical methods are linked with the progress achiev
ed in process metallurgy. The interdisciplinary dialogue that has take
n place between metallurgists and analytical chemists for more than 13
0 years is illustrated by a look at the history of spectroscopy. Summa
ry. Analytical chemistry has been a constant, close companion of metal
lurgy throughout its evolution, and metallurgical processes have partl
y become possible for the first time through the availability of proce
ss-compatible and time-critical analysis methods. The prerequisite for
selectively controlling the basic oxygen steel making process, for ex
ample, has been created by the development of an analysis method that
takes only minutes to perform. The possibilities offered by electronic
data processing have brought the far-reaching automation of spectroan
alytical methods, leading to the creation of comprehensively automated
analysis systems and to unmanned on-line spectrometer lines. There ha
ve, for some years now, been endeavours to use emission spectroscopy f
or the in-line analysis of hot metal and molten steel. This would resu
lt in shorter analysis times an direct information.