Preparing polymer-like materials through supramolecular chemistry is an are
a of growing interest, yet full understanding of how non-covalent forces ma
y be used to prepare such materials is lacking and as a result the success
of these strategies is often serendipitous. Recent examples of discrete one
-dimensional supramolecular fibers employing the most important types of no
n-covalent interactions (metal coordination, hydrogen bonding, pi-pi stacki
ng, hydrophobic effect) illustrate our current ability to prepare these typ
es of materials and point the way for future designs. (C) 2001 Published by
Elsevier Science Ltd.