Preparation of propargylic carbenoids and reactions with carbonyl compounds - A stereoselective synthesis of propargylic halohydrins and oxiranes

Authors
Chemla, F Bernard, N Ferreira, F Normant, JF
Citation
F. Chemla et al., Preparation of propargylic carbenoids and reactions with carbonyl compounds - A stereoselective synthesis of propargylic halohydrins and oxiranes, EUR J ORG C, (17), 2001, pp. 3295-3300
Citations number
27
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
ISSN journal
1434193X → ACNP
Issue
17
Year of publication
2001
Pages
3295 - 3300
Database
ISI
SICI code
1434-193X(200109):17<3295:POPCAR>2.0.ZU;2-5
Abstract
The preparation and the reactivity of the zincioallene 3 is described, This organometallic compound reacts with aldehydes to yield propargylic halohyd rins with good diastereo selectivities. These halohydrins can easily be con verted into propargylic oxiranes.