S. Liu et al., Temperature dependence of coercivity in Sm2TM17 magnets and domain wall motion in magnetic materials, IEEE MAGNET, 37(4), 2001, pp. 2521-2524
It was observed in Sm2TM17 magnets that decreasing Fe content did not stron
gly affect room temperature coercivity but led to a significantly higher co
ercivity at high temperatures; increasing Sm content resulted in much lower
room temperature coercivity but substantially higher coercivity at high te
mperatures; increasing Cu content led to higher coercivity at all temperatu
res. In this paper, the effects of Fe, Sm, and Cu on coercivity are explain
ed by using the temperature dependence of magnetocrystalline anisotropy of
the 2 : 17 cell phase and 1 : 5 cell boundary phase. In order to explain co
mplex temperature dependence of coercivity, thermal activation of domain wa
lls must be taken into account. It is believed that the energy necessary fo
r domain walls to overcome the energy barrier between the 1 : 5 cell bounda
ry phase and 2 : 17 cell phase can be acquired not only from the magnetic H
eld, but also from thermal energy k(B)T. This concept may apply to all magn
etic materials in which domain wall motion is involved during magnetization
and demagnetization processes.