Thermal spin crossover in binuclear Iron(II) helicates: Negative cooperativity and a mixed spin state in solution

Authors
Telfer, SG Bocquet, B Williams, AF
Citation
Sg. Telfer et al., Thermal spin crossover in binuclear Iron(II) helicates: Negative cooperativity and a mixed spin state in solution, INORG CHEM, 40(19), 2001, pp. 4818
Citations number
17
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
INORGANIC CHEMISTRY
ISSN journal
00201669 → ACNP
Volume
40
Issue
19
Year of publication
2001
Database
ISI
SICI code
0020-1669(20010910)40:19<4818:TSCIBI>2.0.ZU;2-A
Abstract
Comparison of the thermal spin crossover transition in solution of a Fe(II) dinuclear triple helicate with the analogous mononuclear complex shows tha t the helicate transition takes place over a wider temperature range in a t wo step process, implying negative cooperativity.