2-(4-ethoxyphenlytelluromethyl)tetrahydro-2H-pyran (L-1) and 2-(2-{4-ethoxyphenyl}telluroethyl)-1,3-dioxane (L-2): synthesis, reactions of L-1 with iodine and ligation of L-1 with Ru(II), Cu(I), and Hg(II) and L-2 with Ru(II). Crystal structures of [RuCl2(p-cymene)center dot L-1/L-2]
Ak. Singh et al., 2-(4-ethoxyphenlytelluromethyl)tetrahydro-2H-pyran (L-1) and 2-(2-{4-ethoxyphenyl}telluroethyl)-1,3-dioxane (L-2): synthesis, reactions of L-1 with iodine and ligation of L-1 with Ru(II), Cu(I), and Hg(II) and L-2 with Ru(II). Crystal structures of [RuCl2(p-cymene)center dot L-1/L-2], INORG CHIM, 320(1-2), 2001, pp. 133-140
2-(4-Ethoxyphenlytelluromethyl)tetrahydro-2H-pyran (L-1) and 2-(2-{4-ethoxy
phenyl}telluroethyl)-1,3-dioxane (L-2) have been synthesized by reacting in
situ generated ArTe-Na+ with an appropriate organic halide. The reaction o
f L-1 with iodine results in its diiodo derivative [L-1(I)(2)] (1). The com
plexes of stoichiometries [CuBrL1] (2), [HgBr2L1] (3) and [RuCl2(p-cymene)-
L-1/L-2] (4/5) are synthesized. The NMR (H-1 and C-13) in conjunction with
elemental analyses, molecular weight and conductance measurements were used
to characterize L, L 2, 1 and the complexes 2-5. The ligands coordinate in
all the complexes through Te, as indicated by the deshielding of CH2Te sig
nals (up to similar to0.8 ppm) with respect to those of free ligands, excep
t in the case of 2 in which bonding through CH2O has also to be invoked. Co
mplexes 4 and 5 are characterized structurally (Ru-Te bond length: 2.619(8)
and 2.642(1) Angstrom, respectively). The Ru-Cl bond lengths are in the ra
nge 2.404(3)-2.420(6) Angstrom. The Te-C(aryl) bond is shorter than the Te-
C(alkyl) bond in 4 but similar in 5. The two Ru(Il) complexes are the first
examples with potential (Te, O) ligands of Ar(R)Te type, which have been s
tructurally characterized. (C) 2001 Elsevier Science B.V. All rights reserv
ed.