Assisted by the interfacial free energy, metastable and fcc phases were for
med by room temperature 200 keV xenon ion mixing of nano-sized multilayers
in the Co-Ag system being immiscible at equilibrium and characterized by a
large positive heat of formation. The formation mechanism of metastable pha
ses is discussed in terms of the far-from-equilibrium process of ion mixing
, the role of the interfacial free energy in enhancing alloying capability
and the effect of valence electrons. (C) 2001 Elsevier Science BV All right
s reserved.