Volumetric properties and phase relations of silica - thermodynamic assessment

Taking into account various available experimental data, an improved intern ally consistent data set for the SiO2 system is obtained by thermodynamic a ssessment. The volumetric properties for SiO2 polymorphs are reassessed usi ng the CALPHAD method. A two-coefficient expression is used to describe the thermal expansion and bulk modulus. For liquid phase, one equation is achi eved in the temperature range of 298-4000 K either for thermal expansion or for bulk modulus. Phase diagrams have been calculated up to 40 GPa. It has been concluded that, in the pressure range lower than 20 GPa, there is no significant difference between the phase diagrams calculated by the Birch-M urnaghan equation of state (EOS) and by Murnaghan EOS. (C) 2001 Elsevier Sc ience B.V. All rights reserved.