M. Ferrandon et al., Copper oxide-platinum/alumina catalysts for volatile organic compound and carbon monoxide oxidation: Synergetic effect of cerium and lanthanum, J CATALYSIS, 202(2), 2001, pp. 354-366
gamma -Alumina alone or modified with 3 mol% additive (La, Ce, or a mixture
of both), on which Pt (0.5 mol%), copper oxide (10 mol% Cu), and CuO-Pt we
re supported, was characterized and tested for the oxidation of a mixture O
f CO, C2H4, and CH4 in excess oxygen. Catalysts were also subjected to vari
ous thermal treatments. Due to its dispersed form, La was more effective th
an Ce in restraining the formation of corundum and copper aluminate. La-Ce
solid solution led to an increase of cerium dispersion and a higher reducib
ility of ceria. Copper dissolved into the cerium lattice, in CuO/Ce-Al2O3,
which, after thermal treatments at 1000 degreesC, produced smaller amounts
of copper aluminate and lower particle size than on CuO/Al2O3. Besides the
presence of surface Cu2+ species dispersed on alumina, on CuO/Ce-Al2O3 temp
erature-programmed reduction evidenced some Cu2+ interacting with ceria. Th
e interaction between Cu and Ce led to stabilization of reduced copper and
an enhancement of copper reducibility, thus leading to a substantial increa
se of CO oxidation for CuO/Ce-Al2O3 catalyst. The oxidation ability of Pt f
or CO and C2H4 was improved by the presence of CuO due to an increase of th
e Pt dispersion and decrease of the Pt particle size. For the oxidation of
CH4 the activities of CuO and CuO-Pt were similar and superior to that of P
t, with or without additives. The presence of Ce decreased the oxidation ac
tivity of the CuO-Pt catalyst due to oxidation of Pt. However, a synergetic
effect between La and Ce in the CuO-Pt/LaCe-Al2O3 catalyst led to more red
uced Pt metal and ceria and a well-dispersed Pt with smaller particle size.
This resulted in a highly active and thermally stable CuO-Pt/La-Ce-Al2O3 c
atalyst for oxidation reactions of model reactants. (C) 2001 Academic Press
.