Mapping the orientation of exciton transition dipoles along individual nanostructures of molecular J-aggregates

Modulation of the polarization state of incident light in reflection micros pectroscopy is used to study locally the orientations of exciton transition dipole moments of fiberlike nanostructures of J-aggregates of pseudoisocya nine dyes. The lowest exciton state assumes a wide range of directions with respect to the long axis of the fibers, from parallel to perpendicular. Th is behavior is correlated with the onset of polariton-like character of the local reflectance spectra. The results imply that a new structural model h as to be conceived to explain the observed phenomena. (C) 2001 American Ins titute of Physics.