The variation of elemental composition in as-grown GaInNAs/GaAs quantum wel
l structures has been investigated by energy dispersive X-ray analysis of c
ross-sections using a high resolution scanning transmission electron micros
cope. The formation of quaternary GaInNAs dot structures is indicated by lo
w temperature photoluminescence measurements and by the correlation of indi
um and nitrogen distributions. The distributions of arsenic and nitrogen ac
ross the well structure suggest the presence of a continuous nitride-like l
ayer formed at the surface of the GaAs buffer layer before the GaInNAs dots
. The influence of this nitride-like interlayer on the mechanism of GaInNAs
dot formation is discussed. (C) 2001 Elsevier Science B.V. All rights rese
rved.