Transition metal sulfur dioxide hexafluoroarsenates and hexafluoroantimonates

Authors
Lork, E Mews, R Petersen, J Schroter, M Zemva, B
Citation
E. Lork et al., Transition metal sulfur dioxide hexafluoroarsenates and hexafluoroantimonates, J FLUORINE, 110(2), 2001, pp. 109-116
Citations number
13
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
JOURNAL OF FLUORINE CHEMISTRY
ISSN journal
00221139 → ACNP
Volume
110
Issue
2
Year of publication
2001
Pages
109 - 116
Database
ISI
SICI code
0022-1139(20010829)110:2<109:TMSDHA>2.0.ZU;2-T
Abstract
The preparation and characterization by X-ray crystallography of transition metal sulfur dioxide hexafluoroarsenates of the general formula [M(SO2)(x) ](AsF6)(2) 1 (1a: M = Mn, x = 2; 1c: M = Co, x = 4; 1e: M = Cu, x = 4) and the hexafluoroantimonate [CO(SO2)(2)](SbF6)(2) 3 is reported. The structura l features of the compounds mentioned are compared with those of [Fe(SO2)(4 )](AsF6)(2) (1b) and [Ni(SO2)(6)](AsF6)(2) (1d), reported previously. The s tructural diversity of transition metal sulfur dioxide complexes is discuss ed. (C) 2001 Elsevier Science B.V. All rights reserved.