NEW REACTION OF THIOCARBONYL YLIDES - INTERACTION OF S-ALKYL-N,N-DIMETHYLTHIOBENZIMIDIUM SALTS WITH ACTIVATED ACETYLENE DERIVATIVES LEADINGTO (E,E)-DIVINYL SULFIDES

Citation
Iv. Magedov et al., NEW REACTION OF THIOCARBONYL YLIDES - INTERACTION OF S-ALKYL-N,N-DIMETHYLTHIOBENZIMIDIUM SALTS WITH ACTIVATED ACETYLENE DERIVATIVES LEADINGTO (E,E)-DIVINYL SULFIDES, Russian chemical bulletin, 46(4), 1997, pp. 759-763
Citations number
16
Categorie Soggetti
Chemistry
Journal title
ISSN journal
10665285
Volume
46
Issue
4
Year of publication
1997
Pages
759 - 763
Database
ISI
SICI code
1066-5285(1997)46:4<759:NROTY->2.0.ZU;2-7
Abstract
The reaction of thiocarbonyl ylides with activated acetylene derivativ es gives (E,E)-divinyl sulfides in good yields. The reaction mechanism is discussed and evidence in favor of the formation of a thiirane int ermediate is presented.