AN UNEXPECTED PATHWAY OF THE REACTION OF LITHIATED 1,1-DIMETHYLALLENEWITH ISOPROPYL ISOTHIOCYANATE

Citation
L. Brandsma et al., AN UNEXPECTED PATHWAY OF THE REACTION OF LITHIATED 1,1-DIMETHYLALLENEWITH ISOPROPYL ISOTHIOCYANATE, Russian chemical bulletin, 46(4), 1997, pp. 832-833
Citations number
7
Categorie Soggetti
Chemistry
Journal title
ISSN journal
10665285
Volume
46
Issue
4
Year of publication
1997
Pages
832 - 833
Database
ISI
SICI code
1066-5285(1997)46:4<832:AUPOTR>2.0.ZU;2-W
Abstract
The reaction of lithiated 1,1-dimethylallene with isopropyl isothiocya nate gives 4,5a-trimethyl-2-methylthio-3H-cyclobuta[b]pyrrole resultin g from cyclization of the intermediate 2,7-dimethyl-4-methylthio-3-aza octa-2,4,6-triene.