ESR STUDY OF RADICAL ADDUCTS OF DIALKOXYPHOSPHORYL RADICALS WITH (ETA(2)-C-60)IRH(CO)(PPH3)(2) AND (ETA(2)-C-60)IRH(C8H12)(PPH3)

Authors
TUMANSKII BL USATOV AV BASHILOV VV SOLODOVNIKOV SP BUBNOV NN NOVIKOV YN SOKOLOV VI
Citation
Bl. Tumanskii et al., ESR STUDY OF RADICAL ADDUCTS OF DIALKOXYPHOSPHORYL RADICALS WITH (ETA(2)-C-60)IRH(CO)(PPH3)(2) AND (ETA(2)-C-60)IRH(C8H12)(PPH3), Russian chemical bulletin, 46(4), 1997, pp. 836-838
Citations number
7
Categorie Soggetti
Chemistry
Journal title
Russian chemical bulletin → ACNP
ISSN journal
10665285
Volume
46
Issue
4
Year of publication
1997
Pages
836 - 838
Database
ISI
SICI code
1066-5285(1997)46:4<836:ESORAO>2.0.ZU;2-D
Abstract
The reaction of phosphoryl radicals with (eta(2)-C-60)IrH(CO)(PPh3)(2) and (eta(2)-C-60)IrH(C8H12)(PPh3) was shown (ESR) to result in the fo rmation of isomers differing in the constants of hyperfine interaction (HFI) with P-31 nuclei, g-factors, and linewidths. It is likely that the addition of phosphoryl radicals at a distance of two-three bond le ngths from the metallofragment is predominant.