Complexes of P(III)-phosphocavitands with Groups VI and VII transition metal carbonyls

Authors
Nifantyev, EE Maslennikova, VI Goryukhina, SE Antipin, MY Lyssenko, KA Vasyanina, LK
Citation
Ee. Nifantyev et al., Complexes of P(III)-phosphocavitands with Groups VI and VII transition metal carbonyls, J ORGMET CH, 631(1-2), 2001, pp. 1-8
Citations number
15
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
JOURNAL OF ORGANOMETALLIC CHEMISTRY
ISSN journal
0022328X → ACNP
Volume
631
Issue
1-2
Year of publication
2001
Pages
1 - 8
Database
ISI
SICI code
0022-328X(20010810)631:1-2<1:COPWGV>2.0.ZU;2-1
Abstract
A study has been made of the interaction between the new type of cavitands, P(III)-phosphocavitands, and the Cr, Mo, W, and Mn carbonyl complexes. The possibility has been shown for the directed coordination of all or some ph osphorus atoms of the cavitand molecules with metals. The effect of the sub stituents at the phosphorus atoms in the macrocycles on the process selecti vity has been revealed. The first metallocomplexes of phosphocavitands cont aining trivalent phosphor-as atoms have been obtained. (C) 2001 Elsevier Sc ience B.V. All rights reserved.