Synthesis and crystal structure of oxo-bridged binuclear titanium complex [{Ti(acac)(2)Cl}{TiCp2(Cl)}(mu-O)] and its catalytic reactions toward silation of aldehyde

Authors
Yun, SS Suh, IH Kim, EH Choi, BJ Lee, S
Citation
Ss. Yun et al., Synthesis and crystal structure of oxo-bridged binuclear titanium complex [{Ti(acac)(2)Cl}{TiCp2(Cl)}(mu-O)] and its catalytic reactions toward silation of aldehyde, J ORGMET CH, 631(1-2), 2001, pp. 16-18
Citations number
16
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
JOURNAL OF ORGANOMETALLIC CHEMISTRY
ISSN journal
0022328X → ACNP
Volume
631
Issue
1-2
Year of publication
2001
Pages
16 - 18
Database
ISI
SICI code
0022-328X(20010810)631:1-2<16:SACSOO>2.0.ZU;2-Y
Abstract
Reaction of [Cp2TiCl2] with two equivalents of 2,4-pentanedione in the pres ence of one equivalent of NEt3 in CH3CN at room temperature yielded oxo-bri dged binuclear titanium complex [{Ti(acac)(2)Cl} {TiCP2(Cl)} (mu -O)], whic h was characterized crystallographically and spectroscopically. Reaction mi xture of oxo-bridged binuclear titanium complex and 2 " BuLi catalytically activate the mixture of phenylsilane and aldehyde to yield O-silation produ cts at room temperature. (C) 2001 Elsevier Science B.V. All rights reserved .