J. Jakubiak et al., Isothermal Photo Differential Scanning Calorimetry - Crosslinking polymerization of multifunctional monomers in presence of visible light photoinitiators, J THERM ANA, 65(2), 2001, pp. 435-443
The effect of photoinitating (camphorquinone/amines) system concentration a
nd sample thickness on the photopolymerization of triethyleneglycol dimetha
crylate/2-hydroxypropyl methacrylate has been investigated. The rate of pho
topolymerization reaches a maximum and then decreases as the concentration
of photoinitiating system increases. This effect has been intepreted as inn
er filter effect.