Synthesis, crystal structure, and magnetic characterization of the double perovskite Ba2MnWO6

Citation
Ak. Azad et al., Synthesis, crystal structure, and magnetic characterization of the double perovskite Ba2MnWO6, MATER RES B, 36(12), 2001, pp. 2215-2228
Citations number
31
Categorie Soggetti
Apllied Physucs/Condensed Matter/Materiales Science","Material Science & Engineering
Journal title
MATERIALS RESEARCH BULLETIN
ISSN journal
00255408 → ACNP
Volume
36
Issue
12
Year of publication
2001
Pages
2215 - 2228
Database
ISI
SICI code
0025-5408(20011001)36:12<2215:SCSAMC>2.0.ZU;2-E
Abstract
The double perovskite Ba2MnWO6 has been prepared as a pure powder by a conv entional solid-state reaction process and studied by X-ray, neutron powder diffraction (NPD), magnetization, and AC susceptibility measurements. NPD, magnetization, and AC susceptibility measurements have been carried out at different temperatures to correlate structural and magnetic properties. Rie tveld analysis of NPD patterns show that the sample is a B-site ordered per ovskite with elpasolite-type structure. At T = 295 K the crystal structure is cubic with a = 8.1985(3) Angstrom, (space group Fm-3m). Temperature-depe ndent magnetization and AC susceptibility measurements show a transition at similar to 45 K to a weak ferromagnetic state, with a spontaneous moment a t 15 K corresponding to mu = 2.2 10(-3) mu (B)/Mn2+. A second transition, t o an antiferromagnetic state, still having a weak spontaneous magnetic mome nt, is detected at similar to9 K. This transition is also confirmed by NPD measurements performed at 4.2 K, showing a number of new distinct magnetic Bragg peaks corresponding to a G-type magnetic structure. (C) 2001 Elsevier Science Ltd. All rights reserved.