Synthesis and structure determination of a piperidinium Zn(HPO4)ClC5H12N

Authors
Rayes, A Ben Nasr, C Rzaigui, M
Citation
A. Rayes et al., Synthesis and structure determination of a piperidinium Zn(HPO4)ClC5H12N, MATER RES B, 36(12), 2001, pp. 2229-2239
Citations number
29
Categorie Soggetti
Apllied Physucs/Condensed Matter/Materiales Science","Material Science & Engineering
Journal title
MATERIALS RESEARCH BULLETIN
ISSN journal
00255408 → ACNP
Volume
36
Issue
12
Year of publication
2001
Pages
2229 - 2239
Database
ISI
SICI code
0025-5408(20011001)36:12<2229:SASDOA>2.0.ZU;2-8
Abstract
This article deals with the synthesis and X-ray structure determination of a new bidimentional zincophosphate (ZnPO) with formula Zn(HPO4)ClC5H12N. Th is phase crystallizes in the orthorhombic space group Pbca (No. 61) with pa rameters: a = 8.767(2) Angstrom; b = 24.678(7) Angstrom; c = 9.322(2) Angst rom; V = 2016.8(1) Angstrom (3); Z = 8. Structure of this compound is deter mined: R = 0.026 R-W = 0.033 and characterized with IR, TGA/DSC, and NMR. T he structure consists of anionic parallel [Zn(HPO4)Cl](-) sheets alternatin g with thick slabs of organic molecules (C5H12N)(+). The organic molecules are linked to the anionic sheets through hydrogen bonds. (C) 2001 Elsevier Science Ltd. All rights reserved.