X-ray fluorescence analysis using synchrotron radiation (SRXRF), X-ray powd
er diffraction, and vibrational spectroscopy had been applied for determina
tion of elemental and mineral composition of human salivary stones. By the
X-ray powder diffraction analysis, the main constituents of salivary stones
were found to be apatite and apatite plus whitlockite. The SRXRF method sh
owed that Ca and P were the major elements, while other microelements such
as Fe, Cu, Zn, Se, Br, Sr, Pb were also detected. The Ca/P molar ratio rang
ed from 1.39 to 2.35. These results were in agreement with the X-ray diffra
ction and vibrational spectroscopy data. (C) 2001 Elsevier Science B.V. All
rights reserved.